Product ID:FREEZALL PLUS SPRAY
MSDS Date:06/01/1994
FSC:6850
NIIN:00N064065
MSDS Number: BYZPJ

CAIG LABORATORIES INC

16744 WEST BERNARDO DR
SAN DIEGO, CA 92127-1904
US

Emergency Phone: 800-441-3637

Info Phone: 619-451-1799

Preparer: MARK K LOHKEMPER

Cage: 55403

CAIG LABORATORIES INC

POWAY, CA 92064 US

Telephone: 858-486-8388

Cage: 55403

1,1,1,2-TETRAFLUOROETHANE

CAS: 811-97-2

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: 1000 PPM (MFR)

AMOUNTS ARE RELEASED. MECHANICAL VENTILATION SHOULD

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:VAP HVR/AIR & CAN CAUSE
SUFFOCATION BY REDUCING OXYGEN AVAIL FOR BRTHG. BRTHG HIGH CONCS OF
VAP MAY CAUSE LT HEAD, DIZZ, SHORTNESS OF BREATH & MAY LEAD TO
NARCOS, CARD IRREG, UNCON/DEATH. LETHARGY & RAPID RESP WERE
OBSERVED AT VAP CONC OF 205,000PPM & PULM CONGESTION, EDEMA & CNS
EFTS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:OCCURRED AT VAP CONC OF 750 PPM. HUMAN
HLTH EFTS OF OVEREXP TO VAPS BY INHAL INCL TEMPORARY CNS DEPRESS
W/ANESTH EFTS (DIZZ, HDCH, CONFUSN, INCOORD & LOSS OF
CONSCIOUSNESS). HIGHER EXPOS TO V APS MAY CAUSE TEMPORARY
ALTERATION OF HEART'S ELEC ACTIVITY W/IRREG PULSE,
PALPITATIONS/INADEQ CIRCULATION/ (SUP DAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM MAY
HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE
EXPOSURES.

First Aid:INGEST:CONSULT MD IF NEC. DO NOT INDUCE VOMIT AS HAZ OF ASPIR
INTO LUNGS GREATER HAZ THAN ALLOWING IT TO PROGRESS THRU INTESTINAL
TRACT. IMHAL:IMMED REMOVE TO FRESH AIR, KEEP CALM, CALL MD. IF NOT
BRT HG GIVE ARTF RESP, PREFERABLY MOUTH-TO-MOUTH. IF BRTHG DFCLT
GIVE OXYGEN. DO NOT GIVE EPINEPHRINE/SIMILAR DRUGS. SKIN:FLUSH
W/WATER. TREAT FOR FROSTBT IF NEC. EYE:IMMED FLUSH W/WATER FOR AT
(SUP DAT)

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:SAME AS OTHER COMBUSTIBLES IN AREA. EXTINGUISHANT
FOR OTHER BURNING MATERIALS IN AREA IS SUFFICIENT TO STOP BURNING.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . COOL FIRE-EXPOSED CONTAINERS WITH WATER
SPRAY.
Unusual Fire/Explosion Hazard:USE WATER SPRAY/FOG TO KEEP CONTRS COOL.
CYL EQUIPPED W/PRESS & TEMP RELIEF DEVICES BUT MAY RUPTURE UNDER
FIRE CNDTNS. DECOMP MAY OCCUR, PROVIDING (SUP DAT)

Spill Release Procedures:VENTILATE AREA UNTIL ODOR IS GONE, ESPECIALLY
LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT. USE NIOSH/MSHA
APPROVED SCBA FOR NECESSARY PROLONGED EXPOSURE. PRODUCT IS HIGHLY
VOLATILE, RAPIDLY EVAPORATES .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT EXPOSE ANY AEROSOL CAN TO
SUNLIGHT OR TEMPERATURES ABOVE 120F TO PREVENT POSSIBLE BURSTING.
Other Precautions:AS WITH ANY CHEMICAL PREPARATION, USE ONLY AS
DIRECTED. AVOID BREATHING VAPORS AND LIQUID CONTACT WITH SKIN OR
EYES. ALL AEROSOL CAUTIONS APPLY. USE IN WELL-VENTILATED AREAS.

Respiratory Protection:UNDER NORMAL CONDITIONS, NO RESPIRATORY
PROTECTION IS REQUIRED WHEN USING THIS PRODUCT. NIOSH/MSHA APPROVED
SCBA IS REQUIRED IF A LARGE RELEASE OCCURS.
Ventilation:NORMAL VENTILATION FOR STANDARD MANUFACTURING PROCEDURES IS
ADEQUATE. LOCAL EXHAUST SHOULD BE USED WHEN LARGE (ING 2)
Protective Gloves:LINED BUTYL GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USE. AVOID BRTHG VAPS & CONT
W/SKIN/EYES. USE ADEQ VENT. WASH HANDS BEFORE EATING,
DRINKING/SMKNG.
Supplemental Safety and Health
EXPLO HAZ: HAZ/TOX BY-PRODS. EFTS OF OVEREXP: FATALITY FROM GROSS
OVEREXP. SKIN CONT W/LIQ MAY CAUSE FROSTBT. FIRST AID PROC: LEAST
15 MIN. CALL MD. NOTE TO MD: BECAUSE OF POSS INCR RISK OF ELICITING
CARD DYSRYTHMIAS, CATACHOLAMINE DRUGS (EPINEPHRINE) SHOULD BE
CONSIDERED ONLY AS LAST RESORT IN LIFE-THREATENING EMER.

Boiling Pt:B.P. Text:-16F,-27C
Vapor Pres:96 PSIA
Vapor Density:3.18
Spec Gravity:1.21
Evaporation Rate & Reference:>1 (CCL*4=1)
Solubility in Water:0.15% APPROX
Appearance and Odor:CLEAR, COLORLESS LIQUID GAS, WITH SLIGHT ETHEREAL
ODOR

Stability Indicator/Materials to Avoid:YES
ALKALI, ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:OPEN FLAMES AND HIGH TEMPERATURES, CONTACT
WITH HOT (GLOWING) SURFACES.
Hazardous Decomposition Products:THIS CMPD CAN BE DECOMP BY HIGH TEMPS
(OPEN FLAME, GLOWING METAL) FORMING HYDROFLUORIC ACIDS & POSS
CARBONYL HALIDES.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.